Experimental Electrochemical Potentials of Nickel Complexes

Abstract Nickel-catalyzed cross-coupling and photoredox catalytic reactions has found widespread utilities in organic synthesis. Redox processes are key intermediate steps many cycles. As a result, it is pertinent to measure document the redox potentials of various nickel species as precatalysts, catalysts, intermediates. The transition-metal complex governed by its oxidation state, ligand, solvent environment. This article tabulates experimentally measured complexes supported on common ligands under conditions. review serves versatile tool help synthetic organometallic chemists evaluate feasibility kinetics events occurring at center, when designing preparing complexes. 1 Introduction 1.1 Scope 1.2 Measurement Formal Potentials 1.3 Nonaqueous Solution 2 Nickel Complexes 2.1 (Phosphine)Ni 2.2 (Nitrogen)Ni 2.3 (NHC)Ni